Effect of disorder on superconductivity of NbN thin films studied using x-ray absorption spectroscopy

نویسندگان

چکیده

The superconducting transition temperature (TC) of rock-salt type niobium nitride (δ- NbN) typically varies between 9 to 17 K and the theoretically predicted value 18 has not been achieved hitherto. lowTCinδ- NbN assigned some structural disorder which is always present irrespective microstructure (polycrystalline or epitaxial), methods conditions adopted during growth thin films. In this work, we investigate atomic origin such suppression theTCinδ- films by employing combined experiments andab initiosimulations. Sputteredδ- with different were studied using synchrotron-based N Nb K-edge x-ray absorption spectroscopy techniques. A strong correlation superconductivity electronic structure reconstruction was observed. theoretical analysis revealed that under N-rich conditions, molecular N-interstitial defects assisted cation vacancies form spontaneously results into a smeared around Fermi-level. role smearing on theTCis thoroughly discussed.

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ژورنال

عنوان ژورنال: Journal of Physics: Condensed Matter

سال: 2021

ISSN: ['0953-8984', '1361-648X']

DOI: https://doi.org/10.1088/1361-648x/ac00dc